Aerospace series - Paints and varnishes - Chromate free (non corrosion inhibiting) two-components cold curing primer - Chromate free primer for military application

This document defines the requirements for a two-components, chromate and lead-free primer.
The coating shall be suitable for use on fibre reinforced composite materials, titanium and corrosion resistant steels and other suitably prepared corrosion resistant substrates.

Luft- und Raumfahrt - Beschichtungsstoffe - Zweikomponenten Grundierung, chromatfrei, nicht korrosionsschützend, raumtemperaturhärtend für militärische Anwendung

Dieses Dokument legt die Anforderungen an eine chromat- und bleifreie Grundbeschichtung fest.
Die Beschichtung wird auf faserverstärkten Verbundstoffen, Titan und korrosionsbeständigem Stahl und anderen geeignet hergestellten korrosionsbeständigen Substraten angewendet.

Série aérospatiale - Peintures et vernis - Peinture primaire sans chromate (non anticorrosion) à deux composants polymérisant à température ambiante - Peinture primaire sans chromate pour applications militaires

Le présent document définit les exigences relatives aux peintures primaires à deux composants, sans chromate ni plomb.
La peinture doit être adaptée à une utilisation sur les matériaux composites renforcés de fibres, le titane et les aciers résistant à la corrosion et autres substrats résistant à la corrosion convenablement préparés.

Aeronavtika - Barve in laki - Brezkromatni (protikorozijski) dvokomponentni temeljni premaz, ki se strdi pri temperaturi okolja - Brezkromatni temeljni premaz za vojaško uporabo

General Information

Status
Published
Publication Date
26-Jan-2021
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
21-Jan-2021
Due Date
28-Mar-2021
Completion Date
27-Jan-2021

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SLOVENSKI STANDARD
SIST EN 4687:2021
01-marec-2021
Nadomešča:
SIST EN 4687:2012
Aeronavtika - Barve in laki - Brezkromatni (protikorozijski) dvokomponentni

temeljni premaz, ki se strdi pri temperaturi okolja - Brezkromatni temeljni premaz

za vojaško uporabo

Aerospace series - Paints and varnishes - Chromate free (non corrosion inhibiting) two-

components cold curing primer - Chromate free primer for military application
Luft- und Raumfahrt - Beschichtungsstoffe - Zweikomponenten Grundierung,
chromatfrei, nicht korrosionsschützend, raumtemperaturhärtend für militärische
Anwendung
Série aérospatiale - Peintures et vernis - Peinture primaire sans chromate (non
anticorrosion) à deux composants polymérisant à température ambiante - Peinture
primaire sans chromate pour applications militaires
Ta slovenski standard je istoveten z: EN 4687:2021
ICS:
49.040 Prevleke in z njimi povezani Coatings and related
postopki, ki se uporabljajo v processes used in aerospace
letalski in vesoljski industriji industry
87.040 Barve in laki Paints and varnishes
SIST EN 4687:2021 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 4687:2021
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SIST EN 4687:2021
EN 4687
EUROPEAN STANDARD
NORME EUROPÉENNE
January 2021
EUROPÄISCHE NORM
ICS 49.040 Supersedes EN 4687:2012
English Version
Aerospace series - Paints and varnishes - Chromate free
(non corrosion inhibiting) two-components room
temperature curing primer - Chromate free primer for
military application

Série aérospatiale - Peintures et vernis - Peinture Luft- und Raumfahrt - Beschichtungsstoffe -

primaire sans chromate (non anticorrosion) à deux Zweikomponenten Grundierung, chromatfrei, nicht

composants polymérisant à température ambiante - korrosionsschützend, raumtemperaturhärtend für

Peinture primaire sans chromate pour applications militärische Anwendung
militaire
This European Standard was approved by CEN on 2 November 2020.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this

European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references

concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN

member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by

translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management

Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 4687:2021 E

worldwide for CEN national Members.
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SIST EN 4687:2021
EN 4687:2021 (E)
Contents Page

European foreword ...................................................................................................................................................... 3

1 Scope .................................................................................................................................................................... 4

2 Normative references .................................................................................................................................... 4

3 Terms and definitions ................................................................................................................................... 6

4 Surface pretreatments .................................................................................................................................. 6

5 Classification..................................................................................................................................................... 7

6 Batch release and qualification testing ................................................................................................... 7

6.1 General................................................................................................................................................................ 7

6.2 Qualification tests ........................................................................................................................................... 7

6.3 Batch acceptance testing .............................................................................................................................. 7

6.4 Purchaser batch release testing ................................................................................................................ 7

7 Requirements for fibre reinforced composites ................................................................................. 17

8 Designation ..................................................................................................................................................... 17

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SIST EN 4687:2021
EN 4687:2021 (E)
European foreword

This document (EN 4687:2021) has been prepared by the Aerospace and Defence Industries

Association of Europe — Standardization (ASD-STAN).

After enquiries and votes carried out in accordance with the rules of this Association, this

document has received the approval of the National Associations and the Official Services of the

member countries of ASD, prior to its presentation to CEN.

This document shall be given the status of a national standard, either by publication of an identical

text or by endorsement, at the latest by July 2021, and conflicting national standards shall be

withdrawn at the latest by July 2021.

Attention is drawn to the possibility that some of the elements of this document may be the subject

of patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

This document supersedes EN 4687:2012.

According to the CEN-CENELEC Internal Regulations, the national standards organizations of the

following countries are bound to implement this document: Austria, Belgium, Bulgaria, Croatia,

Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,

Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,

Turkey and the United Kingdom.
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SIST EN 4687:2021
EN 4687:2021 (E)
1 Scope

This document defines the requirements for a two-components, chromate and lead-free primer.

The coating applies to fibre reinforced composite materials, titanium and corrosion resistant steels and

other suitably prepared corrosion resistant substrates.
2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments) applies.

EN 2101, Aerospace series — Chromic acid anodizing of aluminium and wrought aluminium alloys

EN 2334, Aerospace series — Chromic-sulphuric acid pickle of aluminium and aluminium alloys

EN 2437, Aerospace series — Chromate conversion coatings (yellow) for aluminium and aluminium alloys

EN 3837, Aerospace series — Paints and varnishes — Nature and method for surface preparation of test

pieces in aluminium alloys
EN 3840, Aerospace series — Paints and varnishes — Technical specification

EN 3847, Aerospace series — Paints and varnishes — Determination of sedimentation rating

EN 4160, Aerospace series — Paints and varnishes — Determination of the effect of thermal exposure

EN 4689, Aerospace series — Paints and varnishes — Two-components room temperature curing

polyurethane finish — High flexibility and chemical agent resistance for military application

EN 4704, Aerospace series — Tartaric-Sulphuric-Acid anodizing of aluminium and aluminium wrought

alloys for corrosion protection and paint pre-treatment (TSA)
EN ISO 1513, Paints and varnishes — Examination and preparation of test samples

EN ISO 1518-1, Paints and varnishes — Determination of scratch resistance — Part 1: Constant-loading

method
EN ISO 1519, Paints and varnishes — Bend test (cylindrical mandrel)
EN ISO 1520, Paints and varnishes — Cupping test

EN ISO 1524, Paints, varnishes and printing inks — Determination of fineness of grind

EN ISO 2409, Paints and varnishes — Cross-cut test

EN ISO 2431, Paints and varnishes — Determination of flow time by use of flow cups

EN ISO 2811-1, Paints and varnishes — Determination of density — Part 1: Pycnometer method

EN ISO 2811-2, Paints and varnishes — Determination of density — Part 2: Immersed body (plummet)

method

EN ISO 2811-3, Paints and varnishes — Determination of density — Part 3: Oscillation method

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SIST EN 4687:2021
EN 4687:2021 (E)

EN ISO 2811-4, Paints and varnishes — Determination of density — Part 4: Pressure cup method

EN ISO 2812-1, Paints and varnishes — Determination of resistance to liquids — Part 1: Immersion in

liquids other than water

EN ISO 2812-2, Paints and varnishes — Determination of resistance to liquids — Part 2: Water immersion

method

EN ISO 2813, Paints and varnishes — Determination of gloss value at 20°, 60° and 85°

EN ISO 3251, Paints, varnishes and plastics — Determination of non-volatile-matter content

EN ISO 3675, Crude petroleum and liquid petroleum products — Laboratory determination of density —

Hydrometer method

EN ISO 3679, Determination of flash no-flash and flash point — Rapid equilibrium closed cup method

EN ISO 4628-2, Paints and varnishes — Evaluation of degradation of coatings — Designation of quantity

and size of defects, and of intensity of uniform changes in appearance — Part 2: Assessment of degree of

blistering

EN ISO 6270-1, Paints and varnishes — Determination of resistance to humidity — Part 1: Condensation

(single-sided exposure)

EN ISO 9117-1, Paints and varnishes — Drying tests — Part 1: Determination of through-dry state and

through-dry time

EN ISO 9117-3, Paints and varnishes — Drying tests — Part 3: Surface-drying test using ballotini

EN ISO 9117-6, Paints and varnishes — Drying tests — Part 6: Print-free test

EN ISO 9514, Paints and varnishes — Determination of the pot life of multicomponent coating systems —

Preparation and conditioning of samples and guidelines for testing
EN ISO 11664- , Colorimetry

EN ISO 11890-1, Paints and varnishes — Determination of volatile organic compound (VOC) content —

Part 1: Difference method

EN ISO 11890-2, Paints and varnishes — Determination of volatile organic compound (VOC) content —

Part 2: Gas chromatographic method

ISO 3270, Paints and varnishes and their raw materials — Temperatures and humidities for conditioning

and testing

MIL-PRF-5606H, Performance specification: Hydraulic fluid, petroleum base; aircraft, missile, and

ordnance. (NATO H-515)

MIL-PRF-6081D, Performance specification: Lubricating oil, jet engine. (NATO O-133)

And all its parts quoted in this document.

Published by: DoD National (US) MIL. Department of Defense http://www.defenselink.mil/.

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SIST EN 4687:2021
EN 4687:2021 (E)

MIL-PRF-23699F, Performance specification: Lubricating oil, aircraft turbine engine, synthetic base,

NATO code number O-156

MIL-DTL-83133G, Detail specification: Turbine fuel, aviation, kerosene type, JP-8 (NATO F-34), NATO F-35,

and JP-8+100 (NATO F-37)

AMS 1526B, Cleaner for aircraft exterior surfaces water-miscible, pressure- spraying type

AMS 1527B, Cleaner for aircraft exterior surfaces water-miscible, foam-on, pressure-spraying

AMS 1533A, Cleaner for exterior aircraft surfaces gel-type, solvent-base

DEF STAN 68-10 Issue 5, Corrosion Preventive, Water Displacing NATO Code: C-634 Joint Service

Designation: PX-24
3 Terms and definitions

For the purposes of this document, the terms and definitions given in EN 3840 apply.

ISO and IEC maintain terminological databases for use in standardization at the following addresses:

• ISO Online browsing platform: available at http://www.iso.org/obp
• IEC Electropedia: available at http://www.electropedia.org/
4 Surface pretreatments

In accordance with EN 3837, the surface pretreatments applicable to aluminium alloy test panels are

the following:
EN 3837 Procedure A: Sulfochromic pickling in accordance with EN 2334
EN 3837 Procedure B: Chromic acid anodizing in accordance with EN 2101
EN 3837 Procedure C: Chromate conversion coating in accordance with EN 2437

EN 3837 Procedure D: Tartaric-Sulphuric-Acid anodizing in accordance with EN 4704

Published by: SAE International (US) Society of Automotive Engineers http://www.sae.org/.

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SIST EN 4687:2021
EN 4687:2021 (E)
5 Classification
The primer is classified according to the following types:
TYPE I: Standard solvent content (VOC < 680 g/l)
TYPE II: Low volatile organic content (VOC < 350 g/l)
TYPE III: Waterborne (VOC < 250 g/l)
6 Batch release and qualification testing
6.1 General

The general requirements for qualification and batch release testing shall be in accordance with (i.a.w.)

EN 3840 and the applicable appendix for the specific material.
6.2 Qualification tests

For product qualification, all tests defined in this document, in Table 2 to Table 7, shall be performed.

A minimum of 3 (three) batches shall be tested for qualification purposes.
6.3 Batch acceptance testing

The Manufacturer shall give evidence on the Test Report or the Certificate of Conformance that all the

tests marked with the symbol * in this specification have been performed for batch acceptance tests.

6.4 Purchaser batch release testing

The Purchaser may perform any of the tests of this document deemed necessary to ensure continuing

uniform quality in material shipments.
Table 1 — General requirements
Material description Chromate and lead-free primer for aerospace applications.
Formulation Base Activator Thinner – if appropriate.
These components shall be mixed in simple p
...

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