Interior air of road vehicles - Part 9: Determination of the emissions of volatile organic compounds from vehicle interior parts - Large bag method

This document specifies a large bag sampling method for measuring volatile organic compounds (VOCs), formaldehyde and other carbonyl compounds which are emitted from vehicle interior parts into the air inside road vehicles. This method is intended for evaluation of large new vehicle interior parts, and complete assemblies. This is a screening method to compare similar car components under similar test conditions on a routine basis. Evaluating VOC emissions of vehicle interior parts is an important aspect of the vehicle indoor air quality. This document is complementary to existing standards and provides test laboratories and the manufacturing industry with a cost-effective evaluation of vehicle interior parts. This method is only applicable to newly manufactured vehicle parts. This method is applicable to all types of vehicles, and vehicle products which are used as parts in the interior of vehicles.

Air intérieur des véhicules routiers - Partie 9: Détermination des émissions de composés organiques volatils des parties et matériaux intérieurs des véhicules - Méthode du grand sac

Notranji zrak v cestnih vozilih - 9. del: Določevanje emisij hlapnih organskih spojin iz notranjih delov vozila - Metoda vzorčenja s plinskimi vrečami

Ta dokument določa metodo vzorčenja s plinskimi vrečami za merjenje hlapnih organskih spojin (VOC), formaldehida in drugih karbonilnih spojin, ki se lahko iz notranjih delov vozila izločijo v zrak v cestnih vozilih. Metoda je namenjena ocenjevanju večjih notranjih delov novega vozila in celotnih sklopov. To je presejalna metoda za rutinsko primerjavo podobnih sestavnih delov vozila v podobnih preskusnih pogojih. Ocenjevanje emisij hlapnih organskih spojin iz notranjih delov vozila je pomemben vidik kakovosti zraka v vozilih. Ta dokument dopolnjuje obstoječe standarde in preskusnim laboratorijem ter predelovalni industriji zagotavlja stroškovno učinkovito ocenjevanje notranjih delov vozil. Metoda je uporabna samo za novo izdelane sestavne dele vozil. Uporabna je za vse vrste vozil in avtomobilske izdelke, ki se uporabljajo kot sestavni deli v notranjosti vozil.

General Information

Status
Published
Public Enquiry End Date
09-Oct-2019
Publication Date
05-Nov-2019
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
04-Nov-2019
Due Date
09-Jan-2020
Completion Date
06-Nov-2019

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INTERNATIONAL ISO
STANDARD 12219-9
First edition
2019-04
Interior air of road vehicles —
Part 9:
Determination of the emissions of
volatile organic compounds from
vehicle interior parts — Large bag
method
Air intérieur des véhicules routiers —
Partie 9: Détermination des émissions de composés organiques
volatils des parties et matériaux intérieurs des véhicules — Méthode
du grand sac
Reference number
ISO 12219-9:2019(E)
©
ISO 2019

---------------------- Page: 1 ----------------------
ISO 12219-9:2019(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

---------------------- Page: 2 ----------------------
ISO 12219-9:2019(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Apparatus and materials. 2
5.1 General . 2
5.2 Large sampling bag . 3
5.2.1 General. 3
5.2.2 Material . 3
5.2.3 Air tightness . 3
5.2.4 Bag blank concentration . 3
5.3 Purity of the filling gas . 3
5.4 Thermostatic oven . 3
5.5 Pumps . 4
5.6 Integrating flow meter or gas meter . 4
6 Test conditions . 4
6.1 General . 4
6.2 Vehicle interior parts . 4
6.3 Storage period and storage conditions . 4
6.4 Heating temperature . 5
6.5 Heating time . 5
6.6 Gas amount to be filled in a sampling bag . 5
7 Verification of test conditions . 5
7.1 Monit oring of test conditions . 5
7.2 Recovery rate . 5
8 Test method . 5
8.1 Test equipment . 5
8.2 Preparation for testing . 6
8.2.1 Heated cleaning of sampling bag . 6
8.2.2 Preparation of large sampling bags . 6
8.3 Emission test . 6
8.4 Gas sampling . 7
9 Analysis procedures . 7
9.1 Analysis of VOC . 7
9.2 Analysis of formaldehyde and other carbonyl compounds . 8
10 Calculation of sampling bag values . 8
11 Test report . 8
12 Quality assurance/quality control (QA/QC) .11
Annex A (informative) Summary for heated cleaning process for large sampling bags .12
Annex B (informative) Supplement on test report and recovery rate .13
Bibliography .15
© ISO 2019 – All rights reserved iii

---------------------- Page: 3 ----------------------
ISO 12219-9:2019(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www .iso
.org/iso/foreword .html.
This document was prepared by Technical Committee ISO/TC 146, Air quality, Subcommittee SC 6,
Indoor air.
A list of all parts in the ISO 12219 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/members .html.
iv © ISO 2019 – All rights reserved

---------------------- Page: 4 ----------------------
ISO 12219-9:2019(E)

Introduction
Volatile organic compounds (VOCs) are widely used in industry and can be emitted by many every-day
products and materials. They have attracted much attention in recent years because of their impact
on cabin air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is
important to determine the material emissions of interior parts and to reduce them to an acceptable
level. Therefore, it is important to get comprehensive and reliable information about the types of
organic compounds in the interior air of vehicles and also their concentrations.
This document outlines the sampling bag test method of volatile organic compounds (VOC),
formaldehyde and other carbonyl compounds which diffuse from vehicle interior parts into the air
inside road vehicles.
Measuring VOC from vehicle interior parts can be performed in several ways and the approach selected
depends upon the desired outcome and the material type. For example, to obtain diffusion data from
complete assemblies (e.g. instrument panel, seat, etc.), chambers/bags that have sufficient volume to
house the complete assembly are employed. Meanwhile, to obtain diffusion data from representative
samples of homogeneous vehicle interior materials, micro-scale chamber method can be chosen.
Each measurement method such as bag/micro-scale chamber/small-chamber sampling offers a
complementary approach.
© ISO 2019 – All rights reserved v

---------------------- Page: 5 ----------------------
INTERNATIONAL STANDARD ISO 12219-9:2019(E)
Interior air of road vehicles —
Part 9:
Determination of the emissions of volatile organic
compounds from vehicle interior parts — Large bag method
1 Scope
This document specifies a large bag sampling method for measuring volatile organic compounds
(VOCs), formaldehyde and other carbonyl compounds which are emitted from vehicle interior parts
into the air inside road vehicles. This method is intended for evaluation of large new vehicle interior
parts, and complete assemblies. This is a screening method to compare similar car components under
similar test conditions on a routine basis.
Evaluating VOC emissions of vehicle interior parts is an important aspect of the vehicle indoor air
quality.
This document is complementary to existing standards and provides test laboratories and the
manufacturing industry with a cost-effective evaluation of vehicle interior parts. This method is only
applicable to newly manufactured vehicle parts. This method is applicable to all types of vehicles, and
vehicle products which are used as parts in the interior of vehicles.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 16000-3, Indoor air — Part 3: Determination of formaldehyde and other carbonyl compounds in indoor
air and test chamber air — Active sampling method
ISO 16000-6, Indoor air — Part 6: Determination of volatile organic compounds in indoor and test chamber
air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS or MS-FID
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https: //www .iso .org/obp
— IEC Electropedia: available at http: //www .electropedia .org/
3.1
vehicle interior part
part which is used in the interior of a vehicle including related materials such as adhesives and coating
materials
[SOURCE: ISO 12219-2:2012, 3.1]
© ISO 2019 – All rights reserved 1

---------------------- Page: 6 ----------------------
ISO 12219-9:2019(E)

3.2
sampling bag value
concentration increment of a subject gas component due to the diffusion of VOCs, formaldehyde and
other carbonyl compounds from a vehicle interior part (3.1), multiplied by the total amount of the gas
filled in the sampling bag
[SOURCE: ISO 12219-2:2012, 3.2 modified — “vehicle interior part” replaces “test specimen”.]
3.3
volatile organic compound
VOC
organic compound eluting between and including n-hexane and n-hexadecane on a gas chromatographic
column specified as a 5 % phenyl 95 % methyl polysiloxane capillary column
3.4
total volatile organic compound
TVOC
sum of volatile organic compounds, sampled on Tenax TA®, which elute between and including
n-hexane and n-hexadecane on a non-polar capillary column, detected with a flame ionization detector
(TVOC-FID) or mass spectrometric detector (TVOC-MS), and quantified by converting the total area of
the chromatogram in that analytical window to a nominal mass using the chromatographic response
factor for toluene (toluene equivalents)
[SOURCE: ISO 16000-6:2011, 3.4, modified —Note has been deleted.]
4 Principle
The test method specified in this document describes a procedure for calculating sampling bag values
of VOC, formaldehyde and other carbonyl compounds which can diffuse from vehicle interior parts.
Vehicle interior parts put in a sampling bag are heated at a specified temperature, and then a fraction
of the gas in the sampling bag is collected to measure the test concentrations. By comparing the test
concentrations with the corresponding bag blank concentrations, the sampling bag values of VOC,
formaldehyde and other carbonyl compounds diffusing from vehicle interior parts can be calculated
(see Clause 10).
The analytical part of the overall measurement procedure is based on the use of sorbent tubes with
subsequent thermal desorption and gas chromatographic analysis for VOCs (according to ISO 16000-6)
and the use of 2,4-dinitrophenylhydrazine (DNPH) sorbent tubes, followed by high performance liquid
chromatography (HPLC) analysis with ultraviolet absorption for the determination of formaldehyde
and other carbonyl compounds (according to ISO 16000-3).
The specified analytical procedure is valid for the determination of volatile organic compounds
3 3
(VOCs) ranging in concentration from sub-µg/m to several mg/m . The method is applicable to the
measurement of non-polar and slightly polar VOCs ranging in volatility from n-C to n-C .
6 16
The specified analytical procedure for formaldehyde and other carbonyl compounds is valid for the
3 3
determination of carbonyls within the concentration range of approximately 1 µg/m to 1 mg/m .
5 Apparatus and materials
5.1 General
Test apparatus and materials necessary for determining the sampling bag values of VOC, formaldehyde
and other carbonyl compounds diffusing from vehicle interior parts are mainly as follows:
— sampling bag;
— nitrogen gas or air (filling gas);
2 © ISO 2019 – All rights reserved

---------------------- Page: 7 ----------------------
ISO 12219-9:2019(E)

— thermostatic oven;
— pumps;
— integrating flow meter;
— analytical equipment is described in ISO 16000-3 and ISO 16000-6.
5.2 Large sampling bag
5.2.1 General
Large sampling bags used in this document shall be in accordance with 5.2.2, 5.2.3, 5.2.4 and 7.2.
They shall be low-emitting, low-permeable and low-sorption plastic bags having a capacity of 20 l to
2 000 l used for measuring VOC, formaldehyde and other carbonyl compounds which can emit from
vehicle interior parts. The size of the bag depends on the size of the part and is to be agreed upon
between the parties.
5.2.2 Material
Though no specification is set for the material of a sampling bag, the recommended materials are
fluorinated resin [vinyl fluoride (PVF), polyvinylidene fluoride (PVDF), 4 ethylene fluoride - 6 propylene
fluoride copolymer (FEP)], ethylene-vinyl alcohol copolymer (EVOH). Large sample bags made of just
a single layer of polyethylene terephthalate (PET) or polyolefins (PEHD) can have high permeation
through the bag material. Total film thickness should be above 20 microns.
5.2.3 Air tightness
The large sampling bag shall be sealed airtight using a sealing material such as a tape that will not
affect the test or by the heat seal method so that the gases inside are not mixed with any uncontrolled
outside air.
5.2.4 Bag blank concentration
The bag blank concentration generated by heating a large sampling bag filled with only nitrogen or
air shall be at such a low level as to not affect the test. Each target VOC, collecting 1 l on the sampling
tube, shall have a value less than 20 ng collected on each tube and for formaldehyde and/or any other
carbonyl compound, collecting 3 l on the DNPH cartridge, shall have a value less than 200 ng collected
on each cartridge.
Users should be aware that TVOC bag blank values from bags vary significantly depending on material,
age, cleaning procedure and analytical process. Report specific bag cleaning parameters and all
analytical conditions and calculation methods in order to interpret TVOC report values.
5.3 Purity of the filling gas
For the nitrogen
...

SLOVENSKI STANDARD
SIST ISO 12219-9:2019
01-december-2019
Notranji zrak v cestnih vozilih - 9. del: Določevanje emisij hlapnih organskih spojin
iz notranjih delov vozila - Metoda vzorčenja s plinskimi vrečami
Interior air of road vehicles - Part 9: Determination of the emissions of volatile organic
compounds from vehicle interior parts - Large bag method
Air intérieur des véhicules routiers - Partie 9: Détermination des émissions de composés
organiques volatils des parties et matériaux intérieurs des véhicules - Méthode du grand
sac
Ta slovenski standard je istoveten z: ISO 12219-9:2019
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
43.020 Cestna vozila na splošno Road vehicles in general
SIST ISO 12219-9:2019 en,fr
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
SIST ISO 12219-9:2019

---------------------- Page: 2 ----------------------
SIST ISO 12219-9:2019
INTERNATIONAL ISO
STANDARD 12219-9
First edition
2019-04
Interior air of road vehicles —
Part 9:
Determination of the emissions of
volatile organic compounds from
vehicle interior parts — Large bag
method
Air intérieur des véhicules routiers —
Partie 9: Détermination des émissions de composés organiques
volatils des parties et matériaux intérieurs des véhicules — Méthode
du grand sac
Reference number
ISO 12219-9:2019(E)
©
ISO 2019

---------------------- Page: 3 ----------------------
SIST ISO 12219-9:2019
ISO 12219-9:2019(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

---------------------- Page: 4 ----------------------
SIST ISO 12219-9:2019
ISO 12219-9:2019(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Apparatus and materials. 2
5.1 General . 2
5.2 Large sampling bag . 3
5.2.1 General. 3
5.2.2 Material . 3
5.2.3 Air tightness . 3
5.2.4 Bag blank concentration . 3
5.3 Purity of the filling gas . 3
5.4 Thermostatic oven . 3
5.5 Pumps . 4
5.6 Integrating flow meter or gas meter . 4
6 Test conditions . 4
6.1 General . 4
6.2 Vehicle interior parts . 4
6.3 Storage period and storage conditions . 4
6.4 Heating temperature . 5
6.5 Heating time . 5
6.6 Gas amount to be filled in a sampling bag . 5
7 Verification of test conditions . 5
7.1 Monit oring of test conditions . 5
7.2 Recovery rate . 5
8 Test method . 5
8.1 Test equipment . 5
8.2 Preparation for testing . 6
8.2.1 Heated cleaning of sampling bag . 6
8.2.2 Preparation of large sampling bags . 6
8.3 Emission test . 6
8.4 Gas sampling . 7
9 Analysis procedures . 7
9.1 Analysis of VOC . 7
9.2 Analysis of formaldehyde and other carbonyl compounds . 8
10 Calculation of sampling bag values . 8
11 Test report . 8
12 Quality assurance/quality control (QA/QC) .11
Annex A (informative) Summary for heated cleaning process for large sampling bags .12
Annex B (informative) Supplement on test report and recovery rate .13
Bibliography .15
© ISO 2019 – All rights reserved iii

---------------------- Page: 5 ----------------------
SIST ISO 12219-9:2019
ISO 12219-9:2019(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www .iso
.org/iso/foreword .html.
This document was prepared by Technical Committee ISO/TC 146, Air quality, Subcommittee SC 6,
Indoor air.
A list of all parts in the ISO 12219 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/members .html.
iv © ISO 2019 – All rights reserved

---------------------- Page: 6 ----------------------
SIST ISO 12219-9:2019
ISO 12219-9:2019(E)

Introduction
Volatile organic compounds (VOCs) are widely used in industry and can be emitted by many every-day
products and materials. They have attracted much attention in recent years because of their impact
on cabin air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is
important to determine the material emissions of interior parts and to reduce them to an acceptable
level. Therefore, it is important to get comprehensive and reliable information about the types of
organic compounds in the interior air of vehicles and also their concentrations.
This document outlines the sampling bag test method of volatile organic compounds (VOC),
formaldehyde and other carbonyl compounds which diffuse from vehicle interior parts into the air
inside road vehicles.
Measuring VOC from vehicle interior parts can be performed in several ways and the approach selected
depends upon the desired outcome and the material type. For example, to obtain diffusion data from
complete assemblies (e.g. instrument panel, seat, etc.), chambers/bags that have sufficient volume to
house the complete assembly are employed. Meanwhile, to obtain diffusion data from representative
samples of homogeneous vehicle interior materials, micro-scale chamber method can be chosen.
Each measurement method such as bag/micro-scale chamber/small-chamber sampling offers a
complementary approach.
© ISO 2019 – All rights reserved v

---------------------- Page: 7 ----------------------
SIST ISO 12219-9:2019

---------------------- Page: 8 ----------------------
SIST ISO 12219-9:2019
INTERNATIONAL STANDARD ISO 12219-9:2019(E)
Interior air of road vehicles —
Part 9:
Determination of the emissions of volatile organic
compounds from vehicle interior parts — Large bag method
1 Scope
This document specifies a large bag sampling method for measuring volatile organic compounds
(VOCs), formaldehyde and other carbonyl compounds which are emitted from vehicle interior parts
into the air inside road vehicles. This method is intended for evaluation of large new vehicle interior
parts, and complete assemblies. This is a screening method to compare similar car components under
similar test conditions on a routine basis.
Evaluating VOC emissions of vehicle interior parts is an important aspect of the vehicle indoor air
quality.
This document is complementary to existing standards and provides test laboratories and the
manufacturing industry with a cost-effective evaluation of vehicle interior parts. This method is only
applicable to newly manufactured vehicle parts. This method is applicable to all types of vehicles, and
vehicle products which are used as parts in the interior of vehicles.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 16000-3, Indoor air — Part 3: Determination of formaldehyde and other carbonyl compounds in indoor
air and test chamber air — Active sampling method
ISO 16000-6, Indoor air — Part 6: Determination of volatile organic compounds in indoor and test chamber
air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS or MS-FID
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https: //www .iso .org/obp
— IEC Electropedia: available at http: //www .electropedia .org/
3.1
vehicle interior part
part which is used in the interior of a vehicle including related materials such as adhesives and coating
materials
[SOURCE: ISO 12219-2:2012, 3.1]
© ISO 2019 – All rights reserved 1

---------------------- Page: 9 ----------------------
SIST ISO 12219-9:2019
ISO 12219-9:2019(E)

3.2
sampling bag value
concentration increment of a subject gas component due to the diffusion of VOCs, formaldehyde and
other carbonyl compounds from a vehicle interior part (3.1), multiplied by the total amount of the gas
filled in the sampling bag
[SOURCE: ISO 12219-2:2012, 3.2 modified — “vehicle interior part” replaces “test specimen”.]
3.3
volatile organic compound
VOC
organic compound eluting between and including n-hexane and n-hexadecane on a gas chromatographic
column specified as a 5 % phenyl 95 % methyl polysiloxane capillary column
3.4
total volatile organic compound
TVOC
sum of volatile organic compounds, sampled on Tenax TA®, which elute between and including
n-hexane and n-hexadecane on a non-polar capillary column, detected with a flame ionization detector
(TVOC-FID) or mass spectrometric detector (TVOC-MS), and quantified by converting the total area of
the chromatogram in that analytical window to a nominal mass using the chromatographic response
factor for toluene (toluene equivalents)
[SOURCE: ISO 16000-6:2011, 3.4, modified —Note has been deleted.]
4 Principle
The test method specified in this document describes a procedure for calculating sampling bag values
of VOC, formaldehyde and other carbonyl compounds which can diffuse from vehicle interior parts.
Vehicle interior parts put in a sampling bag are heated at a specified temperature, and then a fraction
of the gas in the sampling bag is collected to measure the test concentrations. By comparing the test
concentrations with the corresponding bag blank concentrations, the sampling bag values of VOC,
formaldehyde and other carbonyl compounds diffusing from vehicle interior parts can be calculated
(see Clause 10).
The analytical part of the overall measurement procedure is based on the use of sorbent tubes with
subsequent thermal desorption and gas chromatographic analysis for VOCs (according to ISO 16000-6)
and the use of 2,4-dinitrophenylhydrazine (DNPH) sorbent tubes, followed by high performance liquid
chromatography (HPLC) analysis with ultraviolet absorption for the determination of formaldehyde
and other carbonyl compounds (according to ISO 16000-3).
The specified analytical procedure is valid for the determination of volatile organic compounds
3 3
(VOCs) ranging in concentration from sub-µg/m to several mg/m . The method is applicable to the
measurement of non-polar and slightly polar VOCs ranging in volatility from n-C to n-C .
6 16
The specified analytical procedure for formaldehyde and other carbonyl compounds is valid for the
3 3
determination of carbonyls within the concentration range of approximately 1 µg/m to 1 mg/m .
5 Apparatus and materials
5.1 General
Test apparatus and materials necessary for determining the sampling bag values of VOC, formaldehyde
and other carbonyl compounds diffusing from vehicle interior parts are mainly as follows:
— sampling bag;
— nitrogen gas or air (filling gas);
2 © ISO 2019 – All rights reserved

---------------------- Page: 10 ----------------------
SIST ISO 12219-9:2019
ISO 12219-9:2019(E)

— thermostatic oven;
— pumps;
— integrating flow meter;
— analytical equipment is described in ISO 16000-3 and ISO 16000-6.
5.2 Large sampling bag
5.2.1 General
Large sampling bags used in this document shall be in accordance with 5.2.2, 5.2.3, 5.2.4 and 7.2.
They shall be low-emitting, low-permeable and low-sorption plastic bags having a capacity of 20 l to
2 000 l used for measuring VOC, formaldehyde and other carbonyl compounds which can emit from
vehicle interior parts. The size of the bag depends on the size of the part and is to be agreed upon
between the parties.
5.2.2 Material
Though no specification is set for the material of a sampling bag, the recommended materials are
fluorinated resin [vinyl fluoride (PVF), polyvinylidene fluoride (PVDF), 4 ethylene fluoride - 6 propylene
fluoride copolymer (FEP)], ethylene-vinyl alcohol copolymer (EVOH). Large sample bags made of just
a single layer of polyethylene terephthalate (PET) or polyolefins (PEHD) can have high permeation
through the bag material. Total film thickness should be above 20 microns.
5.2.3 Air tightness
The large sampling bag shall be sealed airtight using a sealing material such as a tape that will not
affect the test or by the heat seal method so that the gases inside are not mixed with any uncontrolled
outside air.
5.2.4 Bag blank concentration
The bag blank concentration generated by heating a large sampling bag filled with only nitrogen or
air shall be at such a low level as to not affect the test. Each target VOC, collecting 1 l on the
...

SLOVENSKI STANDARD
oSIST ISO 12219-9:2019
01-september-2019
Notranji zrak v cestnih vozilih - 9. del: Določevanje emisij hlapnih organskih spojin
iz notranjih delov vozila - Metoda vzorčenja s plinskimi vrečami
Interior air of road vehicles - Part 9: Determination of the emissions of volatile organic
compounds from vehicle interior parts - Large bag method
Air intérieur des véhicules routiers - Partie 9: Détermination des émissions de composés
organiques volatils des parties et matériaux intérieurs des véhicules - Méthode du grand
sac
Ta slovenski standard je istoveten z: ISO 12219-9:2019
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
43.020 Cestna vozila na splošno Road vehicles in general
oSIST ISO 12219-9:2019 en,fr
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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oSIST ISO 12219-9:2019

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oSIST ISO 12219-9:2019
INTERNATIONAL ISO
STANDARD 12219-9
First edition
2019-04
Interior air of road vehicles —
Part 9:
Determination of the emissions of
volatile organic compounds from
vehicle interior parts — Large bag
method
Air intérieur des véhicules routiers —
Partie 9: Détermination des émissions de composés organiques
volatils des parties et matériaux intérieurs des véhicules — Méthode
du grand sac
Reference number
ISO 12219-9:2019(E)
©
ISO 2019

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oSIST ISO 12219-9:2019
ISO 12219-9:2019(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

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oSIST ISO 12219-9:2019
ISO 12219-9:2019(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Apparatus and materials. 2
5.1 General . 2
5.2 Large sampling bag . 3
5.2.1 General. 3
5.2.2 Material . 3
5.2.3 Air tightness . 3
5.2.4 Bag blank concentration . 3
5.3 Purity of the filling gas . 3
5.4 Thermostatic oven . 3
5.5 Pumps . 4
5.6 Integrating flow meter or gas meter . 4
6 Test conditions . 4
6.1 General . 4
6.2 Vehicle interior parts . 4
6.3 Storage period and storage conditions . 4
6.4 Heating temperature . 5
6.5 Heating time . 5
6.6 Gas amount to be filled in a sampling bag . 5
7 V erification of test conditions . 5
7.1 Monit oring of test conditions . 5
7.2 Recovery rate . 5
8 Test method . 5
8.1 Test equipment . 5
8.2 Preparation for testing . 6
8.2.1 Heated cleaning of sampling bag . 6
8.2.2 Preparation of large sampling bags . 6
8.3 Emission test . 6
8.4 Gas sampling . 7
9 Analysis procedures . 7
9.1 Analysis of VOC . 7
9.2 Analysis of formaldehyde and other carbonyl compounds . 8
10 Calculation of sampling bag values . 8
11 Test report . 8
12 Quality assurance/quality control (QA/QC) .11
Annex A (informative) Summary for heated cleaning process for large sampling bags .12
Annex B (informative) Supplement on test report and recovery rate .13
Bibliography .15
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oSIST ISO 12219-9:2019
ISO 12219-9:2019(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso. org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www .iso
.org/iso/foreword .html.
This document was prepared by Technical Committee ISO/TC 146, Air quality, Subcommittee SC 6,
Indoor air.
A list of all parts in the ISO 12219 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso. org/members .html.
iv © ISO 2019 – All rights reserved

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oSIST ISO 12219-9:2019
ISO 12219-9:2019(E)

Introduction
Volatile organic compounds (VOCs) are widely used in industry and can be emitted by many every-day
products and materials. They have attracted much attention in recent years because of their impact
on cabin air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is
important to determine the material emissions of interior parts and to reduce them to an acceptable
level. Therefore, it is important to get comprehensive and reliable information about the types of
organic compounds in the interior air of vehicles and also their concentrations.
This document outlines the sampling bag test method of volatile organic compounds (VOC),
formaldehyde and other carbonyl compounds which diffuse from vehicle interior parts into the air
inside road vehicles.
Measuring VOC from vehicle interior parts can be performed in several ways and the approach selected
depends upon the desired outcome and the material type. For example, to obtain diffusion data from
complete assemblies (e.g. instrument panel, seat, etc.), chambers/bags that have sufficient volume to
house the complete assembly are employed. Meanwhile, to obtain diffusion data from representative
samples of homogeneous vehicle interior materials, micro-scale chamber method can be chosen.
Each measurement method such as bag/micro-scale chamber/small-chamber sampling offers a
complementary approach.
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oSIST ISO 12219-9:2019
INTERNATIONAL STANDARD ISO 12219-9:2019(E)
Interior air of road vehicles —
Part 9:
Determination of the emissions of volatile organic
compounds from vehicle interior parts — Large bag method
1 Scope
This document specifies a large bag sampling method for measuring volatile organic compounds
(VOCs), formaldehyde and other carbonyl compounds which are emitted from vehicle interior parts
into the air inside road vehicles. This method is intended for evaluation of large new vehicle interior
parts, and complete assemblies. This is a screening method to compare similar car components under
similar test conditions on a routine basis.
Evaluating VOC emissions of vehicle interior parts is an important aspect of the vehicle indoor air
quality.
This document is complementary to existing standards and provides test laboratories and the
manufacturing industry with a cost-effective evaluation of vehicle interior parts. This method is only
applicable to newly manufactured vehicle parts. This method is applicable to all types of vehicles, and
vehicle products which are used as parts in the interior of vehicles.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 16000-3, Indoor air — Part 3: Determination of formaldehyde and other carbonyl compounds in indoor
air and test chamber air — Active sampling method
ISO 16000-6, Indoor air — Part 6: Determination of volatile organic compounds in indoor and test chamber
air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS or MS-FID
3 Terms a nd definiti ons
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https:/ /www. iso .org/obp
— IEC Electropedia: available at http: //www.e lectropedia. org/
3.1
vehicle interior part
part which is used in the interior of a vehicle including related materials such as adhesives and coating
materials
[SOURCE: ISO 12219-2:2012, 3.1]
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oSIST ISO 12219-9:2019
ISO 12219-9:2019(E)

3.2
sampling bag value
concentration increment of a subject gas component due to the diffusion of VOCs, formaldehyde and
other carbonyl compounds from a vehicle interior part (3.1), multiplied by the total amount of the gas
filled in the sampling bag
[SOURCE: ISO 12219-2:2012, 3.2 modified — “vehicle interior part” replaces “test specimen”.]
3.3
volatile organic compound
VOC
organic compound eluting between and including n-hexane and n-hexadecane on a gas chromatographic
column specified as a 5 % phenyl 95 % methyl polysiloxane capillary column
3.4
total volatile organic compound
TVOC
sum of volatile organic compounds, sampled on Tenax TA®, which elute between and including
n-hexane and n-hexadecane on a non-polar capillary column, detected with a flame ionization detector
(TVOC-FID) or mass spectrometric detector (TVOC-MS), and quantified by converting the total area of
the chromatogram in that analytical window to a nominal mass using the chromatographic response
factor for toluene (toluene equivalents)
[SOURCE: ISO 16000-6:2011, 3.4, modified —Note has been deleted.]
4 Principle
The test method specified in this document describes a procedure for calculating sampling bag values
of VOC, formaldehyde and other carbonyl compounds which can diffuse from vehicle interior parts.
Vehicle interior parts put in a sampling bag are heated at a specified temperature, and then a fraction
of the gas in the sampling bag is collected to measure the test concentrations. By comparing the test
concentrations with the corresponding bag blank concentrations, the sampling bag values of VOC,
formaldehyde and other carbonyl compounds diffusing from vehicle interior parts can be calculated
(see Clause 10).
The analytical part of the overall measurement procedure is based on the use of sorbent tubes with
subsequent thermal desorption and gas chromatographic analysis for VOCs (according to ISO 16000-6)
and the use of 2,4-dinitrophenylhydrazine (DNPH) sorbent tubes, followed by high performance liquid
chromatography (HPLC) analysis with ultraviolet absorption for the determination of formaldehyde
and other carbonyl compounds (according to ISO 16000-3).
The specified analytical procedure is valid for the determination of volatile organic compounds
3 3
(VOCs) ranging in concentration from sub-µg/m to several mg/m . The method is applicable to the
measurement of non-polar and slightly polar VOCs ranging in volatility from n-C to n-C .
6 16
The specified analytical procedure for formaldehyde and other carbonyl compounds is valid for the
3 3
determination of carbonyls within the concentration range of approximately 1 µg/m to 1 mg/m .
5 Apparatus and materials
5.1 General
Test apparatus and materials necessary for determining the sampling bag values of VOC, formaldehyde
and other carbonyl compounds diffusing from vehicle interior parts are mainly as follows:
— sampling bag;
— nitrogen gas or air (filling gas);
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oSIST ISO 12219-9:2019
ISO 12219-9:2019(E)

— thermostatic oven;
— pumps;
— integrating flow meter;
— analytical equipment is described in ISO 16000-3 and ISO 16000-6.
5.2 Large sampling bag
5.2.1 General
Large sampling bags used in this document shall be in accordance with 5.2.2, 5.2.3, 5.2.4 and 7.2.
They shall be low-emitting, low-permeable and low-sorption plastic bags having a capacity of 20 l to
2 000 l used for measuring VOC, formaldehyde and other carbonyl compounds which can emit from
vehicle interior parts. The size of the bag depends on the size of the part and is to be agreed upon
between the parties.
5.2.2 Material
Though no specification is set for the material of a sampling bag, the recommended materials are
fluorinated resin [vinyl fluoride (PVF), polyvinylidene fluoride (PVDF), 4 ethylene fluoride - 6 propylene
fluoride copolymer (FEP)], ethylene-vinyl alcohol copolymer (EVOH). Large sample bags made of just
a single layer of polyethylene terephthalate (PET) or polyolefins (PEHD) can have high permeation
through the bag material. Total film thickness should be above 20 microns.
5.2.3 Air tightness
The large sampling bag shall be sealed airtight using a sealing material such as a tape that will not
affect the test or by the heat seal method so that the gases inside are not mixed with any uncontrolled
outside air.
5.2.4 Bag blank concentration
The bag blank concentration generated by heating a large sampling bag filled with only nitrogen or
air shall be at such a low level as to not affect the test. Each target VOC, collecting 1 l on the sam
...

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