M/BC/CEN/91/12 - Dioxin & furan emission

This European Standard specifies the sampling of PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts EN 1948-2 and EN 1948-3 describing extraction and clean-up and identification and quantification, respectively, is necessary for the determination of the PCDDs/PCDFs. This European Standard has been developed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m3 in stationary source emissions. This European Standard specifies both method validation and a framework of quality control requirements which shall be fulfilled by any PCDD/PCDF sampling. The user has the possibility to choose between three different methods: "filter/condenser method" "dilution method" "cooled probe method" Each sampling method is illustrated by some sampling systems described in detail in Annex B as examples of proven procedures. During comparison measurements of the three sampling methods on municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience shows that it can be applied for wide concentration ranges and various emission sources. The procedure described in the three parts of EN 1948 specifies requirements which shall be met in order to measure the 17 congeners necessary to calculate the total I-TEQ (see Table A.1). Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for determination of other low-volatile substances, e.g. of dioxin-like PCBs (details for sampling and analyses see CEN/TS 1948-4), although no validated performance characteristics are available yet.

This European Standard specifies the identification and quantification procedures of the sampled PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts of this standard, EN 1948-1:2006 and EN 1948-2:2006, describing sampling and extraction and clean-up, respectively, is necessary for the determination of the PCDDs/PCDFs. This European Standard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng ITEQ/ m3 in stationary source emissions. This European Standard specifies both method validation and a framework of quality control requirements which shall be fulfilled by any PCDD/PCDF identification and quantification methods to be applied. Some methods are described in detail in Annex A as examples of proven procedures. Each of the three sampling methods (Part 1) can be combined with the extraction and clean-up (Part 2) and the identification and quantification (Part 3) to complete the measurement procedure. During comparison measurements of the three sampling methods on municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience shows that it can be applied for wide concentration ranges and various emission sources. The procedure described in the three parts of EN 1948:2006 specifies requirements in order to measure every 2,3,7,8-chlorine substituted PCDD/PCDF congener required to calculate the total I-TEQ (see Table A.1 of EN 1948-1:2006). Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for determination of other low-volatile substances, e.g. of dioxin-like PCBs (details for sampling and analyses see CEN/TS 1948-4), although no validated performance characteristics are available yet.

This European Standard specifies the extraction and clean-up procedures of the sampled PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts EN 1948-1:2006 and EN 1948-3:2006 describing sampling or identification and quantification, respectively, is necessary for the determination of the PCDDs/PCDFs. This European Standard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m3 in stationary source emissions. This European Standard specifies both method validation and a framework of quality control requirements which shall be fulfilled by any PCDD/PCDF extraction and clean-up methods to be applied. Some methods are described in detail in Annex A as examples of proven procedures. Each of the three sampling methods (Part 1) can be combined with the extraction and clean-up (Part 2) and the identification and quantification (Part 3) to complete the measurement procedure. During comparison measurements of the three sampling methods on municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience shows that it can be applied for wide concentration ranges and various emission sources. The procedure described in the three parts of EN 1948:2006 specifies requirements which shall be met in order to measure the 17 congeners necessary to calculate the total I-TEQ (see Table A.1 of EN 1948-1:2006). Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for determination of other low-volatile substances, e.g. of dioxin-like PCBs (details for sampling and analyses see CEN/TS 1948-4), although no validated performance characteristics are available yet.

This European Standard specifies the identification and quantification procedures of the sampled PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts of this standard, prEN 1948-1:2005 and prEN 1948-2:2005, describing sampling and extraction and clean-up, respectively, is necessary for the determination of the PCDDs/PCDFs.
This European Standard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m3 in stationary source emissions.
This European Standard specifies both method validation and a framework of quality control requirements which shall be fulfilled by any PCDD/PCDF identification and quantification methods to be applied. Some methods are described in detail in Annex A as examples of proven procedures.
Each of the three sampling methods (Part 1) can be combined with the extraction and clean-up (Part 2) and the identification and quantification (Part 3) to complete the measurement procedure.
During comparison measurements of the three sampling methods on municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience shows that it can be applied for wide concentration ranges and various emission sources.
The procedure described in the three parts of  prEN 1948:2005 specifies requirements in order to measure every 2,3,7,8-chlorine substituted PCDD/PCDF congener required to calculate the total I-TEQ (see Table A.1 of prEN 1948-1:2005).
Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for determination of other low-volatile substances, e.g. of dioxin-

This European Standard specifies the extraction and clean-up procedures of the sampled PCDDs/PCDFs. It is integral part of the complete measurement procedure. The use of the other two parts prEN 1948-1:2005 and prEN 1948-3:2005 describing sampling or identification and quantification, respectively, is necessary for the determination of the PCDDs/PCDFs.
This European Standard has been designed to measure PCDD/PCDF concentrations at about
0,1 ng I-TEQ/m3 in stationary source emissions.
This European Standard specifies both method validation and a framework of quality control requirements which shall be fulfilled by any PCDD/PCDF extraction and clean-up methods to be applied. Some methods are described in detail in Annex A as examples of proven procedures.
Each of the three sampling methods (Part 1) can be combined with the extraction and clean-up (Part 2) and the identification and quantification (Part 3) to complete the measurement procedure.
During comparison measurements of the three sampling methods on municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience shows that it can be applied for wide concentration ranges and various emission sources.
The procedure described in the three parts of prEN 1948:2005 specifies requirements which shall be met in order to measure the 17 congeners necessary to calculate the total I-TEQ (see Table A.1 of
prEN 1948-1:2005).
Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for determination of other low-volatile substances, e.g. of dioxin-like PCBs (details for sampling and analyses se

This European Standard specifies the sampling of PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts prEN 1948-2:2005 and
prEN 1948-3:2005 describing extraction and clean-up and identification and quantification, respectively, is necessary for the determination of the PCDDs/PCDFs.
This European Standard has been developed to measure PCDD/PCDF concentrations at about 0,1 ng I TEQ/m3 in stationary source emissions.
This European Standard specifies both method validation and a framework of quality control requirements which shall be fulfilled by any PCDD/PCDF sampling.
The user has the possibility to choose between three different methods:
-   "filter/condenser method"
-   "dilution method"
-   "cooled probe method"
Each sampling method is illustrated by some sampling systems described in detail in Annex B as examples of proven procedures.
During comparison measurements of the three sampling methods on municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience shows that it can be applied for wide concentration ranges and various emission sources.
The procedure described in the three parts of prEN 1948:2005 specifies requirements which shall be met in order to measure the 17 congeners necessary to calculate the total I-TEQ (see Table A.1).
Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for determination of other low-volatile substances, e.g. of dioxin-like PCBs (details for sampling and analyses see CEN/TS 1948-4), although no validated performance characteristics are avail

This part of the Standard specifies the sampling of PCDDs/PCDFs. It is an integral part of the complete measurement procedure.  The use of the other two parts EN 1948-2:1996 and EN 1948-3:1996 describing extraction and clean-up and identification and quantification, respectively, is necessary for the determination of the PCDDs and PCDFs.

The present Part of the Standard specifies the identification and quantificationprocedures of the sampled PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts of this Standard, EN 1948-1:1996 and EN 1948-2:1996, describing sampling and extraction and clean-up, respectively, is necessary for the determination of the PCDDs/PCDFs. This Stan- dard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m cube in stationary source emissions.

Thie present part of this Standard specifies the extraction and clean-up proce- dures of the sampled PCDDs/PCDFs. It is integral part of the complet measurementprocedure. The use of the other two parts EN 1948-1:1996 and EN 1948-3:1996 describing sampling or identification and quantification, respectively, is necessary for the determination of the PCDDs/PCDFs. This standard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m cube in stationary source emissions.

This part of the Standard specifies the sampling of PCDDs/PCDFs. It is an integral part of the complete measurement procedure.  The use of the other two parts EN 1948-2:1996 and EN 1948-3:1996 describing extraction and clean-up and identification and quantification, respectively, is necessary for the determination of the PCDDs and PCDFs.

Thie present part of this Standard specifies the extraction and clean-up proce- dures of the sampled PCDDs/PCDFs. It is integral part of the complet measurementprocedure. The use of the other two parts EN 1948-1:1996 and EN 1948-3:1996 describing sampling or identification and quantification, respectively, is necessary for the determination of the PCDDs/PCDFs. This standard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m cube in stationary source emissions.

The present Part of the Standard specifies the identification and quantificationprocedures of the sampled PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts of this Standard, EN 1948-1:1996 and EN 1948-2:1996, describing sampling and extraction and clean-up, respectively, is necessary for the determination of the PCDDs/PCDFs. This Stan- dard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m cube in stationary source emissions.